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Improvement of the Physical Properties of Polybutylsuccinate Using Stabilizers of Vegetable and Synthetic Origin

  • Flores, Ana [1] ; Carrera, Santiago [2] ; Palmay , Paul [2] ; Jácome, Hugo [2]
    1. [1] Universidad Técnica de Ambato

      Universidad Técnica de Ambato

      Ambato, Ecuador

    2. [2] Escuela Superior Politécnica de Chimborazo, Facultad de Ciencias, Riobamba, Ecuador
  • Localización: Revista Politécnica, ISSN-e 2477-8990, Vol. 55, Nº. 1, 2025 (Ejemplar dedicado a: Revista Politécnica), págs. 71-82
  • Idioma: inglés
  • DOI: 10.33333/rp.vol55n1.07
  • Títulos paralelos:
    • Mejoramiento de las Propiedades Físicas del Polibutilsuccinato Usando Estabilizantes de Origen Vegetal y Sintético
  • Enlaces
  • Resumen
    • español

      La producción de residuos plásticos no degradables ha generado una problemática ambiental bastante grave lo que provoca la búsqueda de polímeros biodegradables que puedan reemplazar a estos plásticos. Uno de estos es el polibutilsuccinato (PBS) que se caracteriza por su buena trabajabilidad, alta resistencia tanto térmica como química, así como alta biocompatibilidad comparable al polietileno. El presente estudio tiene como objetivo el mejoramiento de las propiedades físicas del PBS sintetizado por condensación adicionando estabilizantes vegetales y sintéticos. Se analizó la degradación térmica que sufre el material mediante análisis termogravimétrico y la reología del biopolímero mediante reología rotacional frente a condiciones de trabajo de extrusión para perfiles. Para esto se preparó probetas con polvo de cáscara de patata, ácido ferúlico y luperox. El estudio confirmó que la adición del 5 % en masa de polvo de cáscara de patata al PBS mejora su estabilidad térmica, logró alcanzar valores de velocidad de cizalla para su procesabilidad por extrusión y brinda una oportunidad para copolimerizarse, de tal manera que su uso sea viable.

    • English

      The production of non-degradable plastic waste has generated serious environmental problems, which has motivated the search for biodegradable polymers that can replace plastics. One of these is polybutylsuccinate (PBS), which is characterized by good workability, high thermal and chemical resistance, and high biocompatibility comparable to polyethylene. The objective of this study was to improve the physical properties of PBS synthesized by condensation by adding vegetables and synthetic stabilizers. The thermal degradation suffered by the material was analyzed by thermogravimetric analysis, and the rheology of the biopolymer by rotational rheology against extrusion working conditions. The test tubes were prepared using potato peel powder, ferulic acid, and luperox. The study confirmed that the addition of 5 % by mass of potato peel powder to PBS improves its thermal stability, achieves shear rate values for its processability by extrusion to profiles, and provides an opportunity to copolymerize, in such a way that its use is viable.

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